Glycolaldehyde

  • Glycolaldehyde
  • Hydroxyacetaldehyde
  • 2- Hydroxyethanal
  • Biose

Colorless and odorless powder

Fixed

1.366 g · cm -3 ( 100 ° C)

97 ° C

Poorly in water

Template: Infobox chemical / molecular formula search available

Glycolaldehyde is the simplest compound of the group of hydroxy aldehydes. It has an aldehyde and a hydroxy group. Thus, one can formally associate it with carbohydrates ( Aldodiose ).

Occurrence

Glycolaldehyde generated in the degradation of ethylene glycol in the human body. Furthermore, glycolaldehyde was detected in outer space, including the star system IRAS 16293-2422. It is formed by the reaction of formaldehyde formose and may therefore have originated as early as the prebiotic stage of evolution.

Production and representation

There are a variety of ways to represent glycolaldehyde, for example, by careful oxidation of ethylene by means of hydrogen peroxide in the presence of iron ( II) sulfate.

By catalytic reversal of formaldehyde to glycolaldehyde can be produced from a C1 - module. This reaction is of importance in order to make the C1 - resource base (natural gas, coal, methane hydrates from the deep sea ) for syntheses available.

Properties

Glycolaldehyde is prone to dimerisation to 2,5- dihydroxy-1 ,4-dioxane ( CAS: 23147-58-2, mp: 85 ° C). It will still respond with propenal to ribose, an essential component of ribonucleic acid, and is therefore a precursor to the origin of life.

Use

Glycolaldehyde is the production of polymers containing free hydroxy groups, as well as used as an intermediate for various esters, and aminoalcohols.

269622
de