Molybdenum(III) iodide
Molybdäntriiodid
Black solid
Fixed
927 ° C
Insoluble in water
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Molybdenum (III ) iodide is an inorganic chemical compound of molybdenum from the group of iodides.
Production and representation
Molybdenum (III ) iodide, by reaction of molybdenum hexacarbonyl with iodine at 105 ° C.
Or molybdenum (V ) chloride are obtained in a carbon disulfide solution with hydrogen iodide.
It is also possible the representation of molybdenum and an excess of iodine is at 300 ° C.
Properties
Molybdenum (III ) iodide is a black, antiferromagnetic at room temperature in air -stable solid. In a vacuum, it decomposes at a temperature of 100 ° C in molybdenum (II ) iodide and iodine. It is insoluble in polar and nonpolar solvents. Molybdenum (III ) iodide has a crystal structure isotypic with that of zirconium ( III ) iodide.