Nitrosyl

Nitrosyl is a part of the name of chemical compounds, the NO - or NO - containing ions, for the former term is common. The compounds are derived from nitric oxide NO.

The reduction of nitric oxide results in the at temperatures above -95 ° C unstable hyponitrite anion NO:

When quite easy taking place oxidation of NO produced the nitrosyl or nitrosonium cation NO :

Examples of nitrosyl compounds are:

• Nitrosyl nitrosyl NOF
• Nitrosyl chloride NOCl
• Nitrosyl NOBr

• Black Roussin'sches ammonium salt NH4 [ Fe4S3 (NO) 7]
• Nitrosylsulfuric / Nitrosylhydrogensulfat NOHSO4
• Nitrosyl tetrafluoroborate [ NO] BF4
• Nitrosylcyanid NOCN
• Nitrosylazid NON3
• Nitrosylperchlorat NOClO4
• Nitrosyltricarbonyltriphenyl - phosphinmangan C21H15MnNO4P
• Nitrosyl tris ( triphenylphosphine ) rhodium [( C6H5) 3P ] 3RH (NO)
• Nitrosylhexafluorophosphat NOPF6
• Nitrosobenzene C6H5NO

Nitrosyl salts react with water to form nitrous acid

Organic compounds of the general form R1R2R3C -N = O, which formally from NO - derived ion are referred to as nitroso compounds. A common feature of these compounds is the NO group, which is named as nitroso functional group.

Occurs NO ( nitric oxide so ) or neutral anion or cation as ligand in complexes, then these are sometimes referred to as a metal nitrosyl complex. The nitrosyl ion is isoelectronic with CO, N2 or CN -, has the bond order 3 and acts as a nitrosyl radical on in mononuclear complexes in rare line or angled arrangement.

Swell

• Substance Group
• Nitrosylverbindung