Vanadate

Vanadate are the salts of non-existent in the free form vanadium HxVyOz acids. The vanadates themselves are stable in aqueous solution, the forms occurring on the pH of the solution depend. Some vanadates occur naturally as vanadium minerals, such as Vanadinit, Descloizit and carnotite.

Representation

Many vanadates are of vanadium ( V) oxide by heating with the appropriate amount of a metal oxide represented:

From vanadate can hardly soluble variants - such as ammonium - are precipitated by reaction with another metal salt:

Types of vanadates

Soluble vanadates

In aqueous solutions, many different vanadate ions may be present, the distribution is strongly dependent on pH:

• At pH> 13, the solution contains mainly the tetrahedral orthovanadate anion [ VO4 ] 3 -
• Between pH 7 and 13 appear next to the orthovanadate also divanadate or pyrovanadate [ V2O7 ] 4 - and the metavanadate [ VO 3 ] - on; The lower the pH, the higher is the percentage of protonated anions such as [ HVO4 ] 2 - and [ HV2O7 ] 3 -
• From pH 7 are predominantly orange Decavanadate [ V10O28 ] 6 -, [ HV10O28 ] 5 - and [ H2V10O28 ] 4 - present.

Slightly soluble vanadates

In the industrial production of vanadium is the ammonium NH4VO3 important that as sparingly soluble, yellow, rhombic plates forming compound precipitated upon the addition of ammonium salts from vanadate. With the addition of sodium carbonate ( Na2CO3) or sodium carbonate solution also falls yellow, flaky sodium orthovanadate Na3VO4 from.

Calciumvanadate are obtainable by reaction of calcium oxide ( CaO), vanadium (V ) oxide ( V2O5 ) represented; Selected stoichiometric ratio determines whether this ortho-, pyro - or metavanadates arise.

Similarity to phosphates

The various vanadates are similar structurally and strong in their chemistry, the phosphates; any anions of (partly condensed ) tetrahedra are also constructed, wherein, in the condensation vanadates they are connected through an oxygen bridge. Here, too, exist for the primary orthovanadate ( dihydrogen ), secondary (hydrogen ) and tertiary (non- protonated ) forms. The Divanadate and vanadates have higher depending on the number of protons that can be recorded, and also quaternary pentäre forms.

Vanadatminerale

The group of Vanadatminerale shows Diadochie for a wide variety of similar minerals, in each of which elements of similar ionic radii and the same charge number may be replaced. A naturally occurring vanadate is in the hexagonal crystal system occurs, red-colored Vanadinit with the chemical composition Pb5 ( VO4 ) 3Cl, which forms barrel-shaped crystals. Carnotite uranium or vanadium mica is a yellow to greenish monoclinic mica composition K2 (UO2 ) 2 ( VO4 ) 2.3 H2O. Descloizit may be colored differently, and crystallizes in the orthorhombic crystals with the composition PbZn ( VO4 ) (OH).

Biological significance and Toxicology

Although vanadium is essential for the metabolism, inhibit orthovanadate ( [ VO4 ] 3 -) in higher concentrations, membrane-bound enzymes (P- ATPases and P - type ATPases ) and are therefore toxic to almost all eukaryotes and prokaryotes. This is based on the similarity of vanadate with the phosphate anion. Some aquatic species, such as sea squirts, are able to enrich vanadates from the sea water. These living things contain large amounts of metalloproteins, the so-called Vanabinen containing Vandadium.